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An analytical method for the determination of hydrocarbon and ether emissions from gasoline-, methanol-, and flexible-fueled vehicles is described. This method was used in Phase I of the Auto/Oil Air Quality Improvement Research Program to provide emissions data for various vehicles using individual reformulated gasolines and alternate fuels. These data would then be used for air modeling studies. Emission samples for tailpipe, evaporative, and running loss were collected in Tedlar bags. Gas chromatographic analysis of the emissions samples included 140 components (hydrocarbons, ethers, alcohols and aldehydes) between C1 and C12 in a single analysis of 54-minutes duration. Standardization, quality control procedures, and inter-laboratory comparisons developed and completed as part of this program are also described.

The Multi Material Lightweight Vehicle (MMLV), developed by Magna International and Ford Motor Company, is a result of US Department of Energy project DE-EE0005574. The project demonstrated the lightweighting potential of a five-passenger sedan while maintaining vehicle performance and occupant safety. Prototype vehicles were manufactured and limited full-vehicle testing was conducted. The Mach-I vehicle design, comprised of commercially-available materials and production processes, achieved a 364 kg (23.5%) full-vehicle mass reduction. This resulted in environmental benefits and fuel economy improvements. A significant factor in the overall MMLV mass reduction was the decrease in the powertrain system weight from 340 kg (conventional) to 267 kg (MMLV). This enabled the application of a 1.0-liter three-cylinder engine as the main powerplant. By downsizing the engine, and by implementing material changes within the engine, the weight of the dressed engine was lowered by 29 kg.

While weight reduction in automotive design and manufacturing has been on-going for several years, in the area of powertrain technology lightweighting has been a difficult challenge to overcome due to functional requirements, as well as material and manufacturing constraints. The Multi Material Lightweight Vehicle (MMLV) developed by Magna International and Ford Motor Company is a result of US Department of Energy project DE-EE0005574. The project demonstrates the lightweighting potential of a five passenger sedan, while maintaining vehicle performance and occupant safety. Prototype vehicles were manufactured and limited full vehicle testing was conducted. The Mach-I vehicle design, comprised of commercially available materials and production processes, achieved a 364kg (23.5%) full vehicle mass reduction, enabling the application of a 1.0-liter three-cylinder engine resulting in a significant environmental benefit and fuel reduction.

Phosphorus contamination from engine oil additives has been associated with reduced performance of vehicle-aged exhaust gas catalysts. Identifying phosphorus species on aged catalysts is important for understanding the reasons for catalytic performance degradation. However, phosphorus is present only in small quantities, which makes its detection with bulk analytical techniques difficult. Raman microscopy probes small regions (a few microns in diameter) of a sample, and can detect both crystalline and amorphous materials. It is thus ideal for characterizing phosphates that may have limited distribution in a catalyst. However, suitable Raman spectra for mixed-metal phosphates that might be expected to be present in contaminated catalysts are not generally available.

The exhaust blowdown pulse from each cylinder of a multi-cylinder engine propagates through the exhaust manifold and can affect the in-cylinder pressure of other cylinders which have open exhaust valves. Depending on the firing interval between cylinders connected to the same exhaust manifold, this blowdown interference can affect the exhaust stroke pumping work and the exhaust pressure during overlap, which in turn affects the residual fraction in those cylinders. These blowdown interference effects are much greater for a turbocharged engine than for one which is naturally aspirated because the volume of the exhaust manifolds is minimized to improve turbocharger transient response and because the turbines restrict the flow out of the manifolds. The uneven firing order (intervals of 90°-180°-270°-180°) on each bank of a 90° V8 engine causes the blowdown interference effects to vary dramatically between cylinders.

Speciated HC emissions from the exhaust system of a production engine without an active catalyst have been obtained with 3 sec time resolution during a 70°F cold start using two control strategies. For the conventional cold start, the emissions were initially enriched in light fuel alkanes and depleted in heavy aromatic species. The light alkanes fell rapidly while the lower vapor pressure aromatics increased over a period of 50 sec. These results indicate early retention of low vapor pressure fuel components in the intake manifold and exhaust system. Loss of higher molecular weight HC species does occur in the exhaust system as shown by experiments in which the exhaust system was preheated to 100° C. The atmospheric reactivity of the exhaust HC emissions for photochemical smog formation increases as the engine warms.

An experimental data base of catalyst conversion efficiency was generated, using a tubular flow reactor which contained either a Pt/Rh (5:1; 40g/ft3) or a Pd/Rh (5:1; 40g/ft3) catalyst sample, for the purpose of updating the kinetic rate constants in the Ford TWC model. Steady-state conversion efficiency of CO, NO, C3H8, C3H6, H2 and O2 through these catalysts were determined for a variety of inlet species concentrations and inlet gas temperatures. These data were obtained for values of redox ratio between 0.5 (excess O2) and 4.0, and inlet gas temperatures between 371°C and 593°C. All experimental details and modeling procedures utilized in obtaining an optimized set of kinetic parameters are included. Results of these experiments show significant improvement in CO and NO conversion efficiency and an increase in NH3 production for both catalyst formulations over previous generation catalyst formulations when redox ratio is greater than unity.

A new diesel engine, called the 6.7L Power Stroke® V-8 Turbo Diesel, and code named "Scorpion," was designed and developed by Ford Motor Company for the full-size pickup truck and light commercial vehicle markets. The combustion system includes the piston bowl, swirl level, number of nozzle holes, fuel spray angle, nozzle tip protrusion, nozzle hydraulic flow, and nozzle-hole taper. While all of these parameters could be explored through extensive hardware testing, 3-D CFD studies were utilized to quickly screen two bowl concepts and assess their sensitivities to a few of the other parameters. The two most promising bowl concepts were built into single-cylinder engines for optimization of the rest of the combustion system parameters. 1-D CFD models were used to set boundary conditions at intake valve closure for 3-D CFD which was used for the closed-cycle portion of the simulation.

The development of an integrated Perforated Manifold, Muffler, and Catalyst (PMMC) for an automotive engine exhaust system is described. The design aims to reduce tailpipe emissions and improve engine power while maintaining low sound output levels from the exhaust. The initial design, based on simplified acoustic and fluid dynamic considerations, is further refined through the use of a computational approach and bench tests. A final prototype is fabricated and evaluated using fired engine dynamometer experiments. The results confirm earlier analytical estimates for improved engine power and reductions of emissions and noise levels.

Several types of hybrid-electric vehicles have been developed at Ford Research Laboratory. Among the parallel hybrid systems with a single electric motor, two types were studied. In the first type, the electric motor was attached directly to the crankshaft (mild hybrid) [1], to enable the engine start-stop and regeneration functions. In the second type (full hybrid) the electric motor was connected to the engine through the use of a clutch to allow electric launch of the vehicle and pure electric driving at low speeds. The full hybrid powertrain described in this paper uses a more powerful electric motor for enhanced regenerative braking and engine power assist. An engine-disconnecting clutch saves energy during both the electric propulsion and during vehicle braking. When the clutch is disengaged the engine is shut-off, which eliminates the energy otherwise spent on motoring the engine during electric propulsion.